Cyanide linkage isomerism in cerium(III) and uranium(III) complexes. A relativistic DFT study
نویسندگان
چکیده
منابع مشابه
Properties of Prussian blue materials manifested in molecular complexes: observation of cyanide linkage isomerism and spin-crossover behavior in pentanuclear cyanide clusters.
Pentanuclear, cyanide-bridged clusters [M(tmphen)2]3[M'(CN)6]2 (M/M' = Zn/Cr (1), Zn/Fe (2), Fe/Fe (3), Fe/Co (4), and Fe/Cr (5); tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) were prepared by combining [M'III(CN)6]3- anions with mononuclear complexes of MII ions with two capping tmphen ligands. The clusters consist of a trigonal bipyramidal (TBP) core with three MII ions in the equatorial ...
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ژورنال
عنوان ژورنال: Journal of Organometallic Chemistry
سال: 2017
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2017.03.002